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Extra resources for Advanced Light Source [activity rpt 1997-1998]

Sample text

S. Department of Energy, Oflice of Biological and Environmental Research. 30 Science Hiehli~hts I I Environmental and Earth Sciences BilOSCil ENICES U: PROTIEUINI CFlY$3TALlL0GlRAlF’ lXIY Structural Genomics of M. mctions. mctions derivable tive indicator of itsj%z-tion. k,protein struc- from mutational studies, transcription tracking, turesare ckzu$abh in tem translation tracking, and interaction tracking. ofa$niteset offoh To this end, we are using the Macromolecular associatedwith a smai[lirt offinti”ons.

03–17 ate the influence of soil mineral surface chemistry on g/L as carbon), and completing cations (1 mM the mineral-sorbed organic molecules. -,-.. - . .. . ,. Science Highlights 29 and Earth Sciences ,. - __=. _—T-... =—— . —,. - . _. Figure a b c d I The macromolecular structures of humic substances were affected by solution pH, ionic strength (type and concentration of electrolyte), and the type (fluvial or soil) and concentration of the humic sub- stances. 0 (b). Additions of di- and trivalent cations to humic substances in solution not only promoted their precipitation at a low humic substance concentration, but also modified their molecular structures.

Strated anew technique called multi-atom resonant In thepas~ x-ray techniques such as x-ray absorption, photoemission (WE) x-ray emission, andphotoemission have not been abk to comparable information on neighboring atoms and directly ident~fi the atoms neighboring the absorbing to be applicable over virtually the entire periodic atom, particukzrlyfor atoms that are cibsein atomic table (excluding only hydrogen and helium). numbez Now iW4RPEpromises toprovide much infor- ,’ on that promises to provide In normal resonant photoemission, which is a mation about neighboring atoms, including their iden- well-known intra-atomic process involving only a tities, bondingproperties, and magnetic ordez single atom, the photoelectron signal from a given core energy level (a bound-to-free transition) increas- Spectroscopic techniques that use x rays to excite es sharply when the photon energy matches that core electrons at characteristic photon energies are needed to excite a strong resonant transition from a well known for their elemental, chemical, and mag- lower-energy core level to its first excited state (a netic specificity as far as the absorbing atom is con- bound-to-bound \ 11 cerned.

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Advanced Light Source [activity rpt 1997-1998]


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