By Harkins W. D.
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Extra info for An Electromagnetic Hypothesis of the Kinetics of Heterogeneous Equilibrium, and of the Structure of
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P. Smith, J. Inorg. ,1973, 35, 799. G. N . Papatheodorou, Inorg. , 1973, 12, 1899. N . Islam, Austrul. J . C h e m . , 1973, 26, 2371. B. R. Sundheim and N. Islam, Appl. Spectroscopy, 1973, 27, 2 8 5 . B. R. Sundheim and N. Islam, Appl. Spectroscopy, 1973, 27, 394. M. Gerloch and R. C . Slade, 'Ligand Field Parameters', Cambridge University Press, New York, 1973. C . E. Schaeffer, Strucrure and Bonding, 1973, 14, 69. C . E. Soliverez, Internut. J . , 1973, 7 , 1139. L. G . Boxall, K . W. Fung, and K.
M3 M. Bacci, S . Midollini, P. Stoppioni. and L. Sacconi, Inorg. , 1973, 12, 1801. Electronic Spec fru 23 Ph \ / Ph Ph I 1 PCH,CH,PCH,CH,PCH2CH,P Ph' /Ph \ Ph (3) that all the complexes have square-pyramidal geometry. The Co" and Ni" examples are simple low-spin compounds, but the Fe", though having a singlet ground state, has a thermally accessible triplet, in contrast to all the other known five-co-ordinate complexes of Fe", which have quartet or triplet ground states. Ligand-field parameters obtained from an analysis of the spectrum of the Fe" complex are D q = 2470cm-'.
An Electromagnetic Hypothesis of the Kinetics of Heterogeneous Equilibrium, and of the Structure of by Harkins W. D.